Organic Compound; Aromatic Hydrocarbon; Industrial By-product/Pollutant; Polycyclic Aromatic Hydrocarbon; Pollutant; Food Toxin; Industrial/Workplace Toxin; Natural Compound, ORL-MUS LD50 700 mg kg-1, IPR-MUS LD50 700 mg kg-1, IVN-MUS LD50 56 mg kg-1, Harmful/Irritant/Light Sensitive/Store under Argon, Toxic to aquatic life/Harmful/Irritant/Light Sensitive/Store under Argon, WARNING: Irritates skin and eyes, harmful if swallowed, A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 15 m; Column type: Capillary; Heat rate: 50 K/min; Start T: 50 C; End T: 320 C; End time: 1 min; Start time: 0.5 min; CAS no: 85018; Active phase: CP Sil 8 CB; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vreuls, R.J.J. %PDF-1.4 ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. It has also been used to make bile acids, cholesterol and steroids. (point group D 2h) gives rise to non-degenerate energy lev els (Figure 1(b)). ; Yang, H.; Fang, H.-Z. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. Accessibility Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml('    ') Unable to load your collection due to an error, Unable to load your delegates due to an error. A, 1096, 2005, 76-85. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. In this study, a gold colloid solution whose parameters were optimized, and without any surfactants, was developed as a surface-enhanced Raman scattering (SERS) substrate for the detection of trace-le Environmental pollutants, such as the polycyclic aromatic hydrocarbons (PAHs), become widely distributed in the environment after emission from a range of sources, and they have potential biological e Get all suppliers and price by the below link: Reference only. An analysis of the experimental values" J. Mol. ?7?6MM58VK==K A classic and well established explanation is based on Clar's rule. & Chromatogr. ; Kaiser-Farrell, C.; McCalla, D.R. Chromatogr., 436, 1988, 137-172. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 140 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. The methoxy group at C-4 . : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. They can exist in over 100 different combinations but the most common are treated as a group of 15. ; Kabo, G.J. ; Barcock, R.A.; Lobanov, V.S. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. o|? Soc. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. /Contents 6 0 R Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. Each point on the graph represents mean SD (n = 3 . umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 150 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. ; Vilegas, W., Identification of polycyclic aromatic hydrocarbons in sugar cane soot by gas chromatography-mass spectrometry, Chromatographia, 46(11/12), 1997, 655-663. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 8 K/min; Start T: 50 C; End T: 250 C; End time: 12 min; Start time: 2 min; CAS no: 85018; Active phase: SE-54; Carrier gas: He; Data type: Normal alkane RI; Authors: Harland, B.J. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! 2014-09-30T09:58:39.238reyarbro Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. All except cyclopenta [ a ]phenanthrene have the numbering explicitly depicted (in P-25.1.1 or P-25.2.1; anthracene and phenanthrene in errata). Phenanthrene (CASRN 85-01-8). ; Liang, Y.-Z. Res. and g.c.-m.s. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> /Type/Page Aquat. Dupuy J, et al. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . If you would like a response, please include your email address e.g. In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. 2022 Dec 21;24(1):127. doi: 10.3390/ijms24010127. 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) with formula C14H10, consisting of three fused benzene rings. stream Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. J. Toxicol. Res. ; Ibargoitia, M.L., New components with potential antioxidant and organoleptic properties, detected for the first time in liquid smoke flavoring preparations, J. Agric. /Resources 2 0 R Display controls: Jmol.jmolLink(jmolApplet0,"select all;spacefill 100%; wireframe off;","Spacefill") The HPLC results revealed that four isolated Bacillus spp. A novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms. Commonly, humans are exposed to phenanthrene through inhalation of cigarette smoke but there are many routes of exposure. ; Zhao, C.-X. inhabited the phyllosphere of ornamental plants grown in urban polluted areas. Please sign in to view account pricing and product availability. Chemosphere. XVI. Identification Product Name Phenanthrene Cat No. J. Environ. XXXIV. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. d. There are 12 vibrational degrees of freedom present in . Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. ; Ding, S.F. [9] The complex [Ru(phen)3]2+ is bioactive. and transmitted securely. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Effect and localization of phenanthrene in maize roots. Modify Date: 2023-01-14 19:31:35 JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ About Us | Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. Anthracene is used in the production of the red dye alizarin and other dyes. Phenanthrene induces oxidative stress and inflammation[2]. /Contents 4 0 R and g.c.-m.s. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. Phenanthrene induces oxidative stress and inflammation [2]. Chromatogr., 66, 1972, 43-53. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 280 C; CAS no: 85018; Active phase: HP-5 MS; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. Phenanthroline is a stronger base than bipy. ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. Special Grade. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. . 8600 Rockville Pike ; White, C.M. ChemSpider ID 970. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) endobj Would you like email updates of new search results? Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Nahir, T.M., Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry, J. Chem. Pyrene forms during incomplete combustion of organic compounds. !t^ { 1mJm X>8c_""xpo! Dupuy J, et al. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. ; Lind, M.A., Gas-liquid chromatographic analyses. Description. ; Liang, Y.-Z. Temperature (K) A B C Reference Comment; 373. government site. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. 2018 Jun;237:858-867. It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. lw,n>kwfk`o/Cwd&84Q/;J#]a!. /Producer(Sub Systems, Inc.)/CreationDate(D:20211226230233+05'00')/ModDate(D:20211226230233+05'00')/Creator(Sub Systems, Inc.) X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Jmol.jmolCheckbox(jmolApplet0,"zoom 300","zoom 100","Zoom",false);Jmol.jmolBr() Epub 2019 Jun 21. Chromatogr. ^dm60fg3plI1OrT? Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. 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C, Wang W, Wang RK, Luo X, Hu C Wang. T^ { 1mJm X > 8c_ '' '' xpo Chromatographic Determination of polycyclic aromatic hydrocarbon ( )... Kwfk ` o/Cwd & 84Q/ ; J # ] a!, 2023!

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